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Analisis Energy Produksi Biodiesel dengan Metode Metanol Super Kritis

机译:超临界甲醇法生产生物柴油的能量分析

摘要

Supercritical methanol process has several advantages, that is not influenced by the material conditions for the free fatty acids contained in the materials will be esterified into methyl esters directly, the conversion rate of oil into methyl ester of tall, shorter process time and not influenced by the presence of water. However, this method has a weakness that is the need safety treatment because the process involves high temperatures and pressures. Super critical methanol method has a 2-stage hydrolysis process which took place on the state of the sub critical water to separate the free fatty acid (FFA) and glycerol, methanolyisis place on super critical conditions of methanol with the aim of changing the FFA to biodiesel, both processes take place at a temperature of 270 ° C and pressure of 70-20 MPa.. From the research of biodiesel production process using supercritical methanol without catalyst, the reaction time is faster total reaction time of 9250 seconds (2.57 hours), with the result of more production (400 ml biodiesel) from the raw material 5% water (35 ml ), cooking oil 95% (665 ml), and 95% wt methanol (200 ml), has a 52.39% energy efficiency.
机译:超临界甲醇工艺具有几个优点,不受物料条件的影响,物料中所含的游离脂肪酸将直接酯化成甲酯,油转化成甲酯的转化率高,工艺时间短,不受物料的影响。水的存在。但是,该方法的缺点是需要安全处理,因为该过程涉及高温和高压。超临界甲醇法有一个二级水解过程,该过程在亚临界水的状态下进行,以分离游离脂肪酸(FFA)和甘油,甲醇分解反应在甲醇的超临界条件下进行,目的是将FFA改变为生物柴油,这两个过程都是在270°C的温度和70-20 MPa的压力下进行的。从对使用超临界甲醇无催化剂的生物柴油生产过程的研究中,反应时间更快,总反应时间为9250秒(2.57小时) ,使用5%的水(35 ml),95%的食用油(665 ml)和95%wt的甲醇(200 ml)来生产更多原料(400 ml生物柴油)的结果是,能源效率为52.39%。

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